Product ID:ANCAMINE 1637 CURING AGENT, H1637U
MSDS Date:09/01/1994
FSC:8010
NIIN:00N069289
MSDS Number: CBKGM

AIR PRODUCTS AND CHEMICALS INC

7301 HAMILTON BLVD
ALLENTOWN, PA 18195-1501
US

Emergency Phone: 800-523-9374;215-481-7711

Info Phone: 800-322-9092;800-345-3148

Cage: 00742

AIR PRODUCTS AND CHEMICALS INC

ALLENTOWN, PA 18195-1501 US

Telephone: 800-345-3148/ 800-752-1597

Cage: 00742

PHENOL (SARA 302/313) (CERCLA)

CAS: 108-95-2

RTECS: SJ3327000

Fraction By Weight: <20%

OSHA PEL S, 5 PPM

ACGIH TLV: S, 5 PPM

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

TRIETHYLENETETRAMINE

CAS: 112-24-3

RTECS: YE6650000

Fraction By Weight: <20%

OSHA PEL N/K

ACGIH TLV: N/K

FORMALDEHYDE POLYMER; (FORMALDEHYDE POLYMER WITH PHENOL AND

CAS: 32610-77-8

Fraction By Weight: >60%

OSHA PEL N/K

ACGIH TLV: N/K

SPLASHING/SPLATTERING OF HOT MATL. CAUTION!

RTECS: 9999999ZZ

MAY BE FORMED WHEN PROD COMES IN CONT W/NITROUS ACID,

RTECS: 9999999ZZ

IN FIRE, NITROGEN OXIDE CAN REACT W/WATER

RTECS: 9999999ZZ

PROD UNDER OXYG-STARVED CNDTNS CAN BE EXPECTED TO

RTECS: 9999999ZZ

ISOCYANATES, CYANOGENS, NITROSAMINES, AMIDES,

RTECS: 9999999ZZ

RPTD &/OR PRLNGD EXPOS TO LOW CONC OF VAP

RTECS: 9999999ZZ

PRLNGD CONT W/SKIN MAY CAUSE ALLERGIC RXN/SENSITIZ.

RTECS: 9999999ZZ

ADVERSE EYE EFTS

RTECS: 9999999ZZ

IF SWALLOWED, CALL

RTECS: 9999999ZZ

OR INDUCE VOMIT ONLY AS DIRECTED BY MED PERS. NEVER

RTECS: 9999999ZZ

CLEAN UP PERS MUST BE

RTECS: 9999999ZZ

CLTHG. COVER MINOR SPILLS W/SODIUM BISULFATE TO NEUT

RTECS: 9999999ZZ

ALL PERS REMAIN

RTECS: 9999999ZZ

STREAMS/DRINKING WATER SUPPLIES. NOTIFY LOC HLTH

RTECS: 9999999ZZ

OCCUR. POTNTL FOR CARBON MONOXIDE &/OR NITROUS

RTECS: 9999999ZZ

SYS CAN BE USED DEPENDING ON QUALITY & QTY

RTECS: 9999999ZZ

& DISCHARGE WATER QUALITY STDS. DISPOSE OF IN

RTECS: 9999999ZZ

FORMULATIONS CONTAINING THIS PROD.

RTECS: 9999999ZZ

TRANSFER OR DISCHARGE OF PRODUCT.

RTECS: 9999999ZZ

FULL LENGTH FACESHIELD .

RTECS: 9999999ZZ

LD50 LC50 Mixture:LD50:(ORAL,RAT) >2200 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE:SKIN:CAUSE IRRIT, REDNESS &
DISCOMFORT WHICH IS TRANSIENT. EYES:CAUSE SEV IRRIT & PAIN. RISK OF
EXPOS TO HAZ CONC OF VAP UNDER NORM WORKING CNDTNS IN WELL
VENTILATED SPACE IS MINIMAL. HOWEVER, C NDTNS SUCH AS
SPRAYING/SUDDEN RELEASE OF HOT LIQ, WHICH GENERATE AEROSOL,
MISTS/FOG SHOULD BE AVOIDED. (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ:PROD VAP IN LOW CONC CAN CAUSE
LACRIMATION, CONJUNCT & CORNEAL EDEMA WHEN ABSORBED INTO TISS OF
EYE FROM ATM. CORNEAL EDEMA MAY GIVE RISE TO PERCEPTION OF "BLUE
HAZ"/"FOG" AROUND LIGHTS. EFT IS TRANSIENT & HAS NO KNOWN RESIDUAL
EFT. INGEST MAY CAUSE BLEEDING OF GI TRACT & VOMIT OF BLOOD.
CHRONIC: (ING 9)
Medical Cond Aggravated by Exposure:ASTHMA. EYE DISEASE. SKIN DISORDERS
AND ALLERGIES.

First Aid:EYE:HOLD EYELIDS APART & IMMED FLUSH W/PLENTY OF WATER FOR @
LEAST 15 MINS. CALL PHYS. SKIN:REMOVE PROD & IMMED FLUSH AFFECTED
AREA W/WATER FOR @ LEAST 15 MINS. CALL PHYS. INHAL:MOVE PATIENT TO
FRESH AIR. IF BRTHG HAS STOPPED/IS LABORED GIVE ASSISTED RESP
(E.G. MOUTH-TO-MOUTH). SUPP OXYG MAY BE INDICATED. PVNT ASPIR OF
VOMIT. TURN VICTIM'S HEAD TO SIDE. ASSURE MUCOUS DOES NOT OBSTRUCT
(ING 12)

Flash Point Method:PMCC
Flash Point:277F,136C
Extinguishing Media:IGNIT WILL GIVE RISE TO CLASS B FIRE. IN CASE OF
FIRE USE:WATER SPRAY, CARBON DIOXIDE (CO*2), DRY CHEM, ALCOHOL
FOAM.
Fire Fighting Procedures:NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP .
RETAIN EXPENDED LIQ FROM FIRE FIGHTING FOR LATER DISP. FIREFIGHTERS
SHOULD WEAR BUTYL RUBB BOOTS, (SUPDAT)
Unusual Fire/Explosion Hazard:MAY GENERATE TOXIC OR IRRITATING
COMBUSTION PRODUCTS. SUDDEN REACTION & FIRE MAY RESULT IF PRODUCT
IS MIXED WITH OXIDIZING AGENT.

Spill Release Procedures:CONTAINMENT TECHNIQUES (REMOVAL OF IGNIT
SOURCES, DIKING ETC). STOP LEAK, IF POSS. VENTILATE SPACE INVOLVED.
SHUT OFF/REMOVE ALL IGNIT SOURCES. CONSTRUCT DIKE TO PVNT
SPREADING. COLLECT RUN-OFF WATER & TRANSFER TO DRUMS/TANKS FOR
LATER DISP. (ING 14)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:KEEP IN COOL, DRY, VENTILATED STOR &
IN CLSD CNTNRS. KEEP AWAY FROM OXIDIZERS, HEAT/FLAMES. AVOID BRTHG
OF VAPS. HNDL IN WELL VENTILATED WORK SPACE.
Other Precautions:STORE IN STEEL CNTNRS PREF LOCATED OUTDOORS, ABOVE
GROUND, AND SURROUNDED BY DIKES TO CNTN SPILLS/LEAKS. ADHERE TO
WORK PRACTICE RULES ESTABLISHED BY GOVT REGS (E. G. OSHA). DO NOT
USE SODIUM NITRILE/ OTHER NITROSATING AGENTS IN (ING 21)

Respiratory Protection:IN POORLY VENTILATED AREAS, CARTRIDGE MASK
NIOSH/MSHA APPRVD FOR ORGANIC VAPS IS REC UNDER FOLLOWING
CNDTNS:EMER SITUATION; WHEN PROD VAP CONC IS >20 PPM FOR PERIOD
LONGER THAN 15 MINS; DURING REPAIR & CLEANING OF EQUIP; DURING
(ING 22)
Ventilation:MAINTAIN AIR CONC IN WORK SPACES IN ACCORD W/STDS OUTLINE
IN INGREDS & HLTH HAZ SECTIONS. ADEQ GEN & LOCAL EXHAUST.
Protective Gloves:NITRILE RUBBER GLOVES.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGG & (ING 23)
Other Protective Equipment:IMPERVIOUS CLTHG, SLICKER SUIT, RUBBER
BOOTS. ANSI APPRVD EMERGENCY EYE WASH & DELUGE SHOWER .
Work Hygienic Practices:LAUNDER/DISCARD CONTAMD CLTHG & LEATHER
ARTICLES. EXAMINE PROT GLOVES BEFORE USE. DISCARD IF FIND EVID OF
HOLES/CRACKS.
Supplemental Safety and Health
PH:ALKALINE. FIRE FIGHT PROC:GLOVES. WATERY SPRAY IS ALSO USEFUL IN
COOLING FIRE-EXPOS TANKS & IN DISPERSING VAPS. MATLS TO
AVOID:DICHROMATE) & AQUA REGIA. RXN ACCOMPANIED BY LG HEAT RELEASE
OCCURS WH EN PROD IS MIXED W/ACIDS. HEAT GENERATED MAY BE
SUFFICIENT TO CAUSE VIGOROUS BOILING CREATING HAZ DUE TO (ING 4)

Boiling Pt:B.P. Text:446F,230C
Melt/Freeze Pt:M.P/F.P Text:23.0F,-5.0C
Vapor Pres:<1 @ 20C
Spec Gravity:1.08 @ 25C
pH:SUPDAT
Evaporation Rate & Reference:NOT KNOWN
Solubility in Water:2.5% @ 25C
Appearance and Odor:AMBER VISCOUS LIQUID, FAINT PHENOLIC ODOR.

Stability Indicator/Materials to Avoid:YES
OXIDIZING AGENTS (I.E. PERCHLORATES, NITRATES, ETC.). CLEANING SOLNS,
SUCH AS CHROMERGE (SULFURIC ACID/ (SUPDAT)
Stability Condition to Avoid:NOT APPLICABLE.
Hazardous Decomposition Products:(FROM BURNING, HEATING/RXN W/OTHER
MATERIALS) CO IN A FIRE, CO*2 IN FIRE, AMMONIA WHEN HEATED,
NITROGEN OXIDES (ING 6)

Waste Disposal Methods:COMPLY W/ALL FED, STATE & LOC REGS. INCIN IS
ACCEPTABLE & PREF METH OF DISP. HOWEVER, NITROGEN OXIDE EMISSION
CONTROLS MAY BE REQD TO MEET SPECIFICATIONS. CHEM &/OR BIOLOGICAL
DEGRADATION IS FEASIBLE. SUITABLE INDUST/MUNICIPAL WASTE
TREATMENT(ING 19)

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particular situation.